CIPW

Normative mineralogy is a calculation of the composition of a rock sample that estimates the idealised mineralogy of a rock according to the principles of geochemistry.

Normative mineral calculations can be achieved via either the CIPW Norm or the Barth-Niggli Norm (also known as the Cation Norm).

Normative calculations are used to produce an idealised mineralogy of a crystallized melt. First, a rock is chemically analysed to determine the elemental constituents. Results of the chemical analysis traditionally are expressed as oxides (e.g., weight percent Mg is expressed as weight percent MgO). The normative mineralogy of the rock then is calculated, based upon assumptions about the order of mineral formation and known phase relationships of rocks and minerals, and using simplified mineral formulas. The calculated mineralogy can be used to assess concepts such as silica saturation of melts.

Because the normative calculation is essentially a computation, it can be achieved relatively painlessly via computer programs.

The CIPW Norm was developed in the early 1900s by the petrologists Cross, Iddings, Pirsson and the geochemist Washington. The CIPW normative mineralogy calculation is based on the typical minerals that may be precipitated from an anhydrous melt at low pressure, and simplifies the typical igneous geochemistry seen in nature with the following four constraints:

This is an artificial set of constraints, and therefore the results of the CIPW norm do not reflect the true course of igneous differentiation in nature.

The primary benefit of calculating a CIPW norm is determining what the ideal mineralogy of an aphanitic or porphyritic igneous rock is. Secondly, the degree of silica saturation of the melt that formed the rock can be assessed in the absence of diagnostic feldspathoid species.

The silica saturation of a rock varies not only with silica content but the proportion of the various alkalis and metal species within the melt. The silica saturation eutectic plane is thus different for various families of rocks and cannot be easily estimated, hence the requirement to calculate whether the rock is silica saturated or not.

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