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Bromine gas

Bromine,  35Br
Bromine 25ml (transparent).png
General properties
Pronunciation /ˈbrmn, -mɪn, -mn/ (BROH-meen, -min, -myn)
Appearance reddish-brown
Standard atomic weight (Ar, standard) [79.90179.907] conventional: 79.904
Bromine in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson
Cl

Br

 I 
seleniumbrominekrypton
Atomic number (Z) 35
Group group 17 (halogens)
Period period 4
Element category   reactive nonmetal
Block p-block
Electron configuration [Ar] 3d10 4s2 4p5
Electrons per shell
2, 8, 18, 7
Physical properties
Phase at STP liquid
Melting point 265.8 K ​(−7.2 °C, ​19 °F)
Boiling point 332.0 K ​(58.8 °C, ​137.8 °F)
Density (near r.t.) Br2, liquid: 3.1028 g/cm3
Triple point 265.90 K, ​5.8 kPa
Critical point 588 K, 10.34 MPa
Heat of fusion (Br2) 10.571 kJ/mol
Heat of vaporisation (Br2) 29.96 kJ/mol
Molar heat capacity (Br2) 75.69 J/(mol·K)
Vapour pressure
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 185 201 220 244 276 332
Atomic properties
Oxidation states 7, 5, 4, 3, 1, −1 ​(a strongly acidic oxide)
Electronegativity Pauling scale: 2.96
Ionisation energies
  • 1st: 1139.9 kJ/mol
  • 2nd: 2103 kJ/mol
  • 3rd: 3470 kJ/mol
Atomic radius empirical: 120 pm
Covalent radius 120±3 pm
Van der Waals radius 185 pm
Color lines in a spectral range
Miscellanea
Crystal structure orthorhombic
Orthorhombic crystal structure for bromine
Speed of sound 206 m/s (at 20 °C)
Thermal conductivity 0.122 W/(m·K)
Electrical resistivity 7.8×1010 Ω·m (at 20 °C)
Magnetic ordering diamagnetic
Magnetic susceptibility −56.4·10−6 cm3/mol
CAS Number 7726-95-6
History
Discovery and first isolation Antoine Jérôme Balard and Carl Jacob Löwig (1825)
Main isotopes of bromine
Iso­tope Abun­dance Half-life (t1/2) Decay mode Pro­duct
79Br 51% stable
81Br 49% stable
| references |

Bromine is a chemical element with symbol Br and atomic number 35. It is the third-lightest halogen, and is a fuming red-brown liquid at room temperature that evaporates readily to form a similarly coloured gas. Its properties are thus intermediate between those of chlorine and iodine. Isolated independently by two chemists, Carl Jacob Löwig (in 1825) and Antoine Jérôme Balard (in 1826), its name was derived from the Ancient Greek βρῶμος ("stench"), referencing its sharp and disagreeable smell.

Elemental bromine is very reactive and thus does not occur free in nature, but in colourless soluble crystalline mineral halide salts, analogous to table salt. While it is rather rare in the Earth's crust, the high solubility of the bromide ion (Br) has caused its accumulation in the oceans. Commercially the element is easily extracted from brine pools, mostly in the United States, Israel and China. The mass of bromine in the oceans is about one three-hundredth that of chlorine.

At high temperatures, organobromine compounds readily dissociate to yield free bromine atoms, a process that stops free radical chemical chain reactions. This effect makes organobromine compounds useful as fire retardants, and more than half the bromine produced worldwide each year is put to this purpose. Unfortunately, the same property causes ultraviolet sunlight to dissociate volatile organobromine compounds in the atmosphere to yield free bromine atoms, causing ozone depletion. As a result, many organobromide compounds—such as the pesticide methyl bromide—are no longer used. Bromine compounds are still used in well drilling fluids, in photographic film, and as an intermediate in the manufacture of organic chemicals.


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