Bis(cyclooctadiene)nickel(0)

Bis(cyclooctadiene)nickel(0)

Names
Other names nickel biscod
Identifiers
CAS Number	1295-35-8 Y
3D model (Jmol)	Interactive image
ChemSpider	17215769 Y
ECHA InfoCard	100.013.702
PubChem	6433264
RTECS number	QR6135000
InChI InChI=1S/2C8H8.Ni/c2*1-2-4-6-8-7-5-3-1;/h2*1-2,7-8H2; Y Key: AYHVBQBQROAZHP-UHFFFAOYSA-N Y InChI=1/2C8H8.Ni/c2*1-2-4-6-8-7-5-3-1;/h2*1-2,7-8H2; Key: AYHVBQBQROAZHP-UHFFFAOYAH
SMILES C1C[C][C]CC[C][C]1.C1C[C][C]CC[C][C]1.[Ni]
Properties
Chemical formula	C16H24Ni
Molar mass	275.06 g/mol
Appearance	Yellow solid
Melting point	60 °C (140 °F; 333 K) (decomposes)
Hazards
R-phrases	R10 R40
S-phrases	S36/37
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N  (what is YN ?)
Infobox references

Bis(cyclooctadiene)nickel(0) is the organometallic compound with the formula Ni(C₈H₁₂)₂. This air-sensitive yellow solid is a common source of Ni(0) in chemical synthesis.

Ni(cod)₂, as it is commonly abbreviated, is a diamagnetic coordination complex featuring tetrahedral nickel(0) bound to the alkene groups in two 1,5-cyclooctadiene ligands. The complex is prepared by reduction of anhydrous nickel(II) acetylacetonate in the presence of the diolefin:

Ni(cod)₂ is moderately soluble in benzene and THF. The cod ligands are easily displaced by phosphines, phosphites, and isocyanides.