The nine-volt battery, or 9-volt battery, in its most common form was introduced for the early transistor radios. It has a rectangular prism shape with rounded edges and a polarized snap connector at the top. This type is commonly used in walkie talkies, clocks and smoke detectors.
The nine-volt battery format is commonly available in primary carbon-zinc and alkaline chemistry, in primary lithium iron disulfide, and in rechargeable form in nickel-cadmium, nickel-metal hydride and lithium-ion. Mercury-oxide batteries of this format, once common, have not been manufactured in many years due to their mercury content. Designations for this format include NEDA 1604 and IEC 6F22 (for zinc-carbon) or MN1604 6LR61 (for alkaline). The size, regardless of chemistry, is commonly designated PP3 - a designation originally reserved solely for carbon-zinc - or in some countries, E or E-block.
Most nine-volt alkaline batteries are constructed of six individual 1.5V LR61 cells enclosed in a wrapper. These cells are slightly smaller than LR8D425 AAAA cells and can be used in their place for some devices, even though they are 3.5 mm shorter. Carbon-zinc types are made with six flat cells in a stack, enclosed in a moisture-resistant wrapper to prevent drying. Primary lithium types are made with 3 cells in series.
In 2007, 9-volt batteries accounted for 4% of alkaline primary battery sales in the US. In Switzerland in 2008, 9-volt batteries totalled 2% of primary battery sales and 2% of secondary battery sales.
Other nine-volt batteries of different sizes exist, such as the British "Ever Ready" PP series and certain lantern batteries.
The battery has both terminals in a snap connector on one end. The smaller circular (male) terminal is positive, and the larger hexagonal or octagonal (female) terminal is the negative contact. The connectors on the battery are the same as on the connector itself; the smaller one connects to the larger one and vice versa. The same snap-style connector is used on other battery types in the Power Pack (PP) series. Battery polarization is normally obvious since mechanical connection is usually only possible in one configuration. A problem with this style of connector is that it is very easy to connect two batteries together in a short circuit, which quickly discharges both batteries, generating heat and possibly a fire. Because of this hazard, 9-volt batteries should be kept in the original packaging until they are going to be used. An advantage is that several nine-volt batteries can be connected to each other in series to provide higher voltages.