The 2014 National League Division Series was two best-of-five-game series to determine the participating teams in the 2014 National League Championship Series. The Washington Nationals, Los Angeles Dodgers, and St. Louis Cardinals (seeded 1–3 based on record, respectively) and San Francisco Giants—played in two series. Fox Sports 1 carried most of the games, with two of the games on MLB Network.

These matchups were:

This was the first postseason meeting between the Nationals and Giants. The Dodgers and Cardinals met in the postseason for the fifth time, with the Cardinals having won three of the first four matchups, including the previous year's NLCS which the Cardinals won 4 games to 2.

San Francisco won the series, 3–1.

St. Louis won the series, 3–1.

The Giants opened the series with Jake Peavy on the mound to counter Nationals starter Stephen Strasburg. Joe Panik put the Giants on the board in the third inning with an RBI single and Brandon Belt followed suit in the fourth to support Peavy, who didn't allow a hit until the bottom of the fifth inning. The first signs of trouble for the Giants came in the bottom of the sixth when, after a leadoff double from former Giant Nate Schierholtz and a two-out walk to Jayson Werth, Peavy was taken out of the game. Javier López came into the game only to surrender a walk to Adam LaRoche. With the bases loaded, Hunter Strickland came on to make just his tenth overall Major League appearance and struck out Ian Desmond to end the threat. The Giants added a third run when Panik tripled to lead off the seventh, and Buster Posey singled to knock him in. This run was to prove crucial, as when Strickland came out in the bottom half of the inning, he allowed solo home runs to both Bryce Harper and Asdrúbal Cabrera to make it a one-run game. Jeremy Affeldt finished off the Nationals in the seventh, and Sergio Romo pitched a scoreless eighth, before Santiago Casilla retired the side in order for the save, as the Giants held on to win by a score of 3–2.

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