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Names | |||
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Preferred IUPAC name
1,1-Difluoroethane
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Other names
Difluoroethane
Freon 152a Ethylidene difluoride Ethylidene fluoride HFC-152a R-152a DFE |
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Identifiers | |||
75-37-6 | |||
3D model (Jmol) | Interactive image | ||
ChEMBL | ChEMBL325493 | ||
ChemSpider | 6128 | ||
ECHA InfoCard | 100.000.788 | ||
PubChem | 6368 | ||
RTECS number | KI1410000 | ||
UNII | 0B1U8K2ME0 | ||
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Properties | |||
C2H4F2 | |||
Molar mass | 66.05 g/mol | ||
Density | 2.7014 g/L @ 25 °C | ||
Melting point | −117 °C (−179 °F; 156 K) | ||
Boiling point | −25 °C (−13 °F; 248 K) | ||
0.54% @ 0 °C | |||
Vapor pressure | 4020 mmHg/536 kPa @ 21.1 °C
5.1 bar/510 kPa @ 20 °C |
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Viscosity | 0.00887 cP (8.87 µPa·s) @ 25 °C | ||
Hazards | |||
Safety data sheet | MSDS for 1,1-difluoroethane | ||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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what is ?) | (|||
Infobox references | |||
5.1 bar/510 kPa @ 20 °C
1,1-Difluoroethane, or DFE, is an organofluorine compound with the chemical formula C2H4F2. This colorless gas is used as a refrigerant, where it is often listed as R-152a (refrigerant-152a) or HFC-152a (hydrofluorocarbon-152a). As an alternative to chlorofluorocarbons, it has an ozone depletion potential of zero, a lower global warming potential (120) and a shorter atmospheric lifetime (1.4 years). It has recently been approved for use in automobile applications as an alternative to R-134a.
1,1-Difluoroethane is produced by the mercury-catalyzed addition of hydrogen fluoride to acetylene:
The intermediate in this process is vinyl fluoride, the monomeric precursor to polyvinyl fluoride.
In addition to serving as a refrigerant, 1,1-difluoroethane is also commonly used in gas duster (commonly thought of as "canned air") and many consumer aerosol products, especially those subject to stringent VOC requirements.
The molecular weight of difluoroethane is 66, making it useful and convenient tool for detecting vacuum leaks in GC-MS systems.
The practice of deliberately inhaling or “huffing” canned air can be fatal. It caused a fatal cardiac arrhythmia in a 42-year-old man. Several reports of fatal car crashes have been linked to drivers huffing 1,1-difluoroethane. Because of inhalant abuse, a bitterant is added to consumer canned air products.