Philosophy of chemistry

The philosophy of chemistry considers the methodology and underlying assumptions of the science of chemistry. It is explored by philosophers, chemists, and philosopher-chemist teams. For much of its history, philosophy of science has been dominated by the philosophy of physics, but the philosophical questions that arise from chemistry have received increasing attention since the latter part of the 20th century.

Major philosophical questions arise as soon as one attempts to define chemistry and what it studies. Atoms and molecules are often assumed to be the fundamental units of chemical theory, but traditional descriptions of molecular structure and chemical bonding fail to account for the properties of many substances, including metals and metal complexes and aromaticity.

Additionally, chemists frequently use non-existent chemical entities like resonance structures to explain the structure and reactions of different substances; these explanatory tools use the language and graphical representations of molecules to describe the behavior of chemicals and chemical reactions that in reality do not behave as straightforward molecules.

Some chemists and philosophers of chemistry prefer to think of substances, rather than microstructures, as the fundamental units of study in chemistry. There is not always a one-to-one correspondence between the two methods of classifying substances. For example, many rocks exist as mineral complexes composed of multiple ions that do not occur in fixed proportions or spatial relationships to one another.

A related philosophical problem is whether chemistry is the study of substances or reactions. Atoms, even in a solid, are in perpetual motion and under the right conditions many chemicals react spontaneously to form new products. A variety of environmental variables contribute to a substance's properties, including temperature and pressure, proximity to other molecules and the presence of a magnetic field. As Schummer puts it, "Substance philosophers define a chemical reaction by the change of certain substances, whereas process philosophers define a substance by its characteristic chemical reactions."

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