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Gluconasturtiin

Gluconasturtiin
Gluconasturtiin Structural Formulae V.4.svg
Names
IUPAC name
{[3-phenyl-1-{[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6- (hydroxymethyl)-2-tetrahydropyranyl]thio}propylidene]amino} hydrogen sulfate
Other names
Phenethylglucosinolate
Identifiers
499-30-9 YesY
3D model (Jmol) Interactive image
ChemSpider 7827541 N
PubChem 9548618
UNII 163ENC977A N
Properties
C15H21NO9S2
Molar mass 423.461 g/mol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N  (what is YesYN ?)
Infobox references

Gluconasturtiin (phenethylglucosinolate) is one of the most widely distributed glucosinolates in the cruciferous vegetables, mainly in the roots, and is probably one of the plant compounds responsible for the natural pest-inhibiting properties of growing crucifers, such as cabbage, mustard or rape, in rotation with other crops. This effect of gluconasturtiin is most likely due to its degradation by the plant enzyme myrosinase into phenethyl isothiocyanate, which is toxic to many organisms.

Gluconasturtiin is named from its occurrence in watercress (Nasturtium officinale). Among the vegetables, it is also found in horseradish (Armoracia rusticana) along with sinigrin. Both compounds elicit a pungent taste.

In one investigation of horseradish roots, sinigrin concentration represented 83% and gluconasturtiin 11% of the extracted glucosinolates.



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Wikipedia

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