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UV degradation


Many natural and synthetic polymers are attacked by ultraviolet radiation, and products using these materials may crack or disintegrate if they are not UV-stable. The problem is known as UV degradation, and is a common problem in products exposed to sunlight. Continuous exposure is a more serious problem than intermittent exposure, since attack is dependent on the extent and degree of exposure.

Many pigments and dyes can also be affected, and the problem known as phototendering can affect textiles such as curtains or drapes.

Common synthetic polymers that can be attacked include polypropylene and LDPE, where tertiary carbon bonds in their chain structures are the centres of attack. Ultraviolet rays interact with these bonds to form free radicals, which then react further with oxygen in the atmosphere, producing carbonyl groups in the main chain. The exposed surfaces of products may then discolour and crack, and in extreme cases, complete product disintegration can occur.

In fibre products like rope used in outdoor applications, product life will be low because the outer fibres will be attacked first, and will easily be damaged by abrasion for example. Discolouration of the rope may also occur, thus giving an early warning of the problem.

Polymers which possess UV-absorbing groups such as aromatic rings may also be sensitive to UV degradation. Aramid fibres like Kevlar, for example, are highly UV-sensitive and must be protected from the deleterious effects of sunlight.


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