Cohesion (chemistry)

Cohesion (from Latin cohaerere "stick or stay together") or cohesive attraction or cohesive force is the action or property of like molecules sticking together, being mutually attractive. It is an intrinsic property of a substance that is caused by the shape and structure of its molecules, which makes the distribution of orbiting electrons irregular when molecules get close to one another, creating electrical attraction that can maintain a microscopic structure such as a water drop. In other words, cohesion allows for surface tension, creating a "solid-like" state upon which light-weight or low-density materials can be placed.

Water, for example, is strongly cohesive as each molecule may make four hydrogen bonds to other water molecules in a tetrahedral configuration. This results in a relatively strong Coulomb force between molecules. In simple terms, the polarity (state of which a molecule is oppositely charged on its poles) of water molecules allows them to be attracted towards each other. The polarity is due to the electronegativity of the atom of oxygen ; oxygen is more electronegative than the atoms of hydrogen, so the electrons they share through the covalent bonds are more often close to oxygen rather than hydrogen: these are called polar covalent bonds, covalent bonds between atoms that thus become oppositely charged. In the case of a water molecule, the hydrogen atoms carry positive charges while the oxygen atom has a negative charge. This charge polarization within the molecule allows it to align with adjacent molecules through strong intermolecular hydrogen bonding, rendering the bulk liquid cohesive. Van der Waals gases such as methane, however, have weak cohesion due only to Van der Waals forces that operate by induced polarity in non-polar molecules.

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